Pep Guardiola endured a torrid return to Barcelona with Manchester City, as they were crushed 4-0 at the Camp Nou.
Lionel Messi, back in Luis Enrique’s starting line-up after recovering from injury, capitalized on a defensive mix-up to open scoring.
The Argentine finished the night with a hat-trick. Although Neymar missed from the spot, he made up for it with an exquisite goal late on.
Mesut Ozil netted his first career hat-trick, as Arsenal ran riot at the Emirates, hammering Ludogorets 6-0.
In other matches played on Wednesday, Paris Saint-Germain defeated Basel 3-0, Napoli lost 3-2 at home to Besiktas, Atletico Madrid won 1-0 at Rostov and Benfica beat Dynamo Kyiv 2-0.
Bayern Munich claimed a 4-1 win over PSV and Borussia Mochengladbach defeated Celtic 2-0.
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